Measure theoretic entropy of the system of hard spheres

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We numerically calculate the configurational entropy Sconf of a binary mixture of hard spheres, by using a perturbed Hamiltonian method trapping the system inside a given state, which requires less assumptions than the previous methods [R.J. Speedy, Mol. Phys. 95, 169 (1998)]. We find that Sconf is a decreasing function of packing fraction φ and extrapolates to zero at the Kauzmann packing frac...

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ژورنال

عنوان ژورنال: Ergodic Theory and Dynamical Systems

سال: 1988

ISSN: 0143-3857,1469-4417

DOI: 10.1017/s0143385700004363